Hexaaquamagnesium(II) bis{[2-(1-phenyl-1H-tetrazol-5-yl)sulfanyl]acetate}
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چکیده
The asymmetric unit of the title compound, [Mg(H(2)O)(6)](C(9)H(7)N(4)O(2)S)(2), contains one-half of a [Mg(H(2)O)(6)](2+) cation ( symmetry) and one uncoordinated 2-[(1-phenyl-1H-tetra-zol-5-yl)sulfan-yl]acetate anion. The Mg(II) cation is coordinated by six water mol-ecules, exhibiting a slightly distorted octa-hedral coordination. A two-dimensional network parallel to (001) is formed via extensive hydrogen-bonding inter-actions involving the water mol-ecules as donors and the tetra-zole N and carboxyl-ate O atoms of the anion as acceptors. The shortest distance between two adjacent parallel benzene rings is 3.315 (2) Å. The dihedral angle between the benzene ring and the tetra-zole ring is 40.98 (2)°.
منابع مشابه
Hexaaquamagnesium(II) bis{5-[3-(1H-tetrazol-5-yl)phenyl]tetrazolide} tetrahydrate
The asymmetric unit of the title compound, [Mg(H(2)O)(6)](C(8)H(5)N(8))(2)·4H(2)O, contains one half of the centrosymmetric dication, one anion and two water mol-ecules. The Mg(II) ion is coordinated by six water mol-ecules in a slightly distorted octa-hedral geometry. In the anion, the two five-membered heterocycles are twisted from the central benzene ring by 4.34 (11) and 3.20 (10)°. In the ...
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In the title compound, [Cd(C(3)H(3)N(4)O(2))(2)](n), the Cd(II) ion, located on a twofold rotation axis, is six-coordinated by two N atoms [Cd-N = 2.368 (2) Å] and four O atoms [Cd-O = 2.300 (1) and 2.260 (1) Å] from six 2-(1H-tetra-zol-1-yl)acetate (L) ligands in a distorted octa-hedral geometry. The metal centres are connected via the tridentate L ligands into a three-dimensional polymeric st...
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متن کاملcatena-Poly[(trans-diaquacadmium)-bis{μ-5-[4-(1H-imidazol-1-yl)phenyl]tetrazol-1-ido}]
In the title compound, [Cd(C(10)H(7)N(6))(2)(H(2)O)(2)], the Cd(II) atom lies on an inversion centre and is coordinated by four N atoms from 5-[4-(1H-imidazol-1-yl)phen-yl]tetra-zol-1-ide ligands and two O atoms from the coordinated water mol-ecules in an octa-hedral arrangement. The complex polymeric chains are inter-connected via inter-molecular water O-H⋯N hydrogen bonds into a three-dimensi...
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